The Snamprogetti Urea Process is basically a total recycle stripping process using ammonia as a self-stripping agent. The Snamprogetti process used the excess ammonia present in the urea solution leaving the reactor to strip CO2 from urea solution in a falling film steam heated heat exchanger operated at the urea reactor pressure. The separated CO2 and NH3 are recombined as ammonium carbamate in the carbamate condensers, also operating at urea reactor pressure and then returned to the reactor for conversion to urea.
The overall result of this scheme is that an internal recycle of both NH3 and CO2 in the urea reactor system is established without having to pump either component, as in the previous total recycle process in which NH3 and CO2 were separated from the solution at lower pressure. This substantially reduces the high-pressure pumping requirements for both the NH3 and ammonium carbamide solution, since in the Snamprogetti stripping process approximately 80% of the CO2 fed is converted to urea within high-pressure synthesis loop and only about 20% of it must be pumped back to the reactor as ammonium carbamate solution from a lower pressure. In addition to the reducing pumping requirements, this process permits a substantial saving in the steam requirement, since the operating temperature level of the ammonium carbamate condenser by utilizing the heat released by the condensing vapour.
The NH3 to CO2 ratio used in Snamprogetti process is 3.3-3.6: 1which combines with a temperature of 186-189deg C and pressure of 155 Kg/cm2g approximately, permits a conversion yield in the reactor of 62 to 65%. Plant layout
The overall result of this scheme is that an internal recycle of both NH3 and CO2 in the urea reactor system is established without having to pump either component, as in the previous total recycle process in which NH3 and CO2 were separated from the solution at lower pressure. This substantially reduces the high-pressure pumping requirements for both the NH3 and ammonium carbamide solution, since in the Snamprogetti stripping process approximately 80% of the CO2 fed is converted to urea within high-pressure synthesis loop and only about 20% of it must be pumped back to the reactor as ammonium carbamate solution from a lower pressure. In addition to the reducing pumping requirements, this process permits a substantial saving in the steam requirement, since the operating temperature level of the ammonium carbamate condenser by utilizing the heat released by the condensing vapour.
The NH3 to CO2 ratio used in Snamprogetti process is 3.3-3.6: 1which combines with a temperature of 186-189deg C and pressure of 155 Kg/cm2g approximately, permits a conversion yield in the reactor of 62 to 65%. Plant layout
Block diagram of total recycling of ammonia stripping in urea production:
Urea production takes place through the following main operations:
- Urea synthesis and high-pressure recovery.
- Urea purification in the medium, low pressure decomposers, pre-vacuum concentrators. Urea concentration.
- Urea Prilling.
The liquid ammonia coming from the battery limit at a temperature of 12oC and 18 Kg/cm2(g) is collected in an ammonia receiving vessel which is operated at medium pressure(17Kg/cm2). From the ammonia receiver, the liquid ammonia is pumped to the reactor by two pumps. The first pump is the ammonia booster pump which is the centrifugal type and supplies the liquid ammonia at 22Kg/cm2 to the second pump suction. The second pump is the high-pressure ammonia pump which is a reciprocating-plunger type. Due to the reciprocating motion of second pump pulsating takes place in the discharge of booster pump and those cause the change of loads on booster pump to avoid these booster pumps and those cause the change of loads on booster pump to avoid these pulsations a damper is provided in the suction of the second pump. In the H.P. ammonia pump, the ammonia pressure is increased to 239Kg/cm2 and then goes to an ammonia preheater where it is preheated to 75oC by L.P. decomposer outlet gases, H.P. ammonia is used as pressure section contains first and second stage another one is the high-pressure section contains third and the fourth stage. First and second stages contain three, the third stage contains four and fourth stage two numbers of closed type impellers. Carbon dioxide gas enters first stage suction at 1.5kg/cm2 and 40oC and compressed to 160 Kg/cm2 in four stages. Intercoolers are provided after the first, second and third stages to cool the carbon dioxide using cooling water. Along with coolers knock-out drums are provided between each stage in which moisture gets separated. Lube oil system provides the lubrication of the rotating parts. The superheated steam and saturated LS steam is used as a driving fluid for a steam turbine. Superheated HS steam is extracted and part of steam is condensed in a condenser. Condensate is then pumped to D.M. plant.
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| Flow sheet of Urea prilling system |
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| Block diagram of urea prilling section |
