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Mass Transfer Operation Humidification


Humidifier Calculator



Cooling tower working model, water and air flow
 Humidification: Cooling Tower
Model

Have you ever wondered how humidification works? It's actually a process that involves the transfer of material between a pure liquid phase and a fixed gas that doesn't dissolve in the liquid. As the gas flows through the liquid, it reaches a special temperature called the adiabatic saturation temperature. Interestingly, the temperature of the gas is always higher than the temperature measured by a wet bulb thermometer, which is why it's called the dry bulb temperature. But what really matters is the relative humidity, which is the ratio of the partial pressure of the vapor to the vapor pressure of the liquid at the gas temperature. This is what determines how humid or dry the air feels!

Operation of cooling tower which cools the hot water to wet bulb temperature
Cooling Tower
Operation
When it comes to humidity, there's a subtle difference between percentage humidity and relative humidity. Unless the air is completely dry or fully saturated, the percentage humidity will always be lower than the relative humidity. But what's really interesting is how heat affects humidity. The amount of heat needed to raise the temperature of a pound of gas and its accompanying vapor by just one degree Fahrenheit is known as humid heat, and it's measured in BTUs. A great example of humidification in action is a cooling tower, where hot water is cooled down by exposing it to air. For instance, if you have water at 95°F and you want to cool it down to 80°F, you can use a cooling tower to do the job. By exposing the water to air with a wet-bulb temperature of 70°F, the water will be cooled down to the desired temperature, making it a perfect example of humidification in action


The heat required to vaporize 1 lb of water is roughly 1000 BTU. The lowest temperature to which water can be cooled in a cooling tower throughout the year depends on the maximum wet bulb temperature. The adiabatic saturation line and wet bulb temperature line are the same for the system air–water. If a warm vapour-gas mixture is contacted with cold liquid so that the humidity of the gas is sensible heat transfer will occur from the gas to the liquid. The purge of a small amount of water from a cooling tower is necessary in order to keep the load on the cooling tower at a specified level and keep the dissolved salt concentration at a specified level. The Dewpoint of a gas-vapor mixture (for a fixed vapor mole – fraction in gas) increases with an increase in pressure.


Evaporative Cooling: A Cooling Process

During evaporative cooling, the wet bulb temperature remains constant, but the partial pressure of vapor and relative humidity increase. This process involves recirculating water, which helps to cool the air through evaporation. As the water evaporates, it absorbs heat from the air, cooling it down. This process is commonly used in cooling towers and evaporative coolers.

Cooling a Gas-Vapor Mixture

When a gas-vapor mixture is cooled through sensible heat transfer, the relative humidity decreases, and the wet bulb temperature also decreases. This is because the cooling process reduces the amount of vapor in the mixture, which in turn reduces the relative humidity. The wet bulb temperature, which is a measure of the heat loss due to evaporation, also decreases as the mixture is cooled.

Condensation: The Beginning of a New Phase

Condensation occurs when the partial pressure of vapor in a mixture equals the saturation vapor pressure of the liquid. This is the point at which the vapor begins to condense into liquid droplets. For example, when the partial pressure of water vapor in the air equals the saturation vapor pressure of water at a given temperature, condensation begins to occur.

Adiabatic Saturation: A Process of Cooling and Humidification

During adiabatic saturation, the wet bulb temperature remains substantially constant. This process involves passing unsaturated air through a water spray chamber, which cools and humidifies the air. The wet bulb temperature, which is a measure of the heat loss due to evaporation, remains constant during this process. For instance, if an unsaturated air-water vapor mixture at a dry bulb temperature of 40°C is passed through a water spray chamber maintained at 17°C, the air will be cooled and dehumidified, resulting in a decrease in wet bulb temperature.

A Real-World Example

Let's consider an example to illustrate this concept. Suppose we have an unsaturated air-water vapor mixture at a dry bulb temperature of 40°C. The dew point for this mixture is 20°C. If we pass this mixture through a water spray chamber maintained at 17°C, the air will be cooled and dehumidified. As a result, the wet bulb temperature will decrease, indicating a reduction in the heat loss due to evaporation. This process is commonly used in air conditioning and cooling systems to control the temperature and humidity of the air.



The mathematical model for a humidifier can be based on the following assumptions:

1. Counter-flow configuration: The air and water flows are in opposite directions.
2. Steady-state operation: The system is operating at a steady state.
3. Negligible heat losses: The heat losses to the surroundings are negligible.

The following equations can be used to model the humidifier:

Energy Balance

  • m_da \* h_a + m_dw \* h_w = m_da \* h_a_out + m_dw \* h_w_out

where:

- m_da is the mass flow rate of dry air
- m_dw is the mass flow rate of water
- h_a is the specific enthalpy of air
- h_w is the specific enthalpy of water
- h_a_out is the specific enthalpy of air at the outlet
- h_w_out is the specific enthalpy of water at the outlet

Mass Balance

  • m_da \* ω_a + m_dw = m_da \* ω_a_out

where:

- ω_a is the humidity ratio of air
- ω_a_out is the humidity ratio of air at the outlet



Here's a sample MATLAB code to solve the above equations:


% Given parameters
m_da = 1;  % mass flow rate of dry air (kg/s)
m_dw = 0.1;  % mass flow rate of water (kg/s)
T_a_in = 25;  % inlet air temperature (C)
T_w_in = 20;  % inlet water temperature (C)
ω_a_in = 0.01;  % inlet air humidity ratio

% Constants
C_pa = 1005;  % specific heat capacity of air (J/kg/K)
C_pw = 4186;  % specific heat capacity of water (J/kg/K)
h_fg = 2454e3;  % latent heat of vaporization (J/kg)

% Calculate outlet temperatures and humidity ratio
T_a_out = T_a_in + (m_dw / m_da) \* (T_w_in - T_a_in);
T_w_out = T_w_in - (m_da / m_dw) \* (T_a_out - T_a_in);
ω_a_out = ω_a_in + (m_dw / m_da);

% Calculate specific enthalpies
h_a_in = C_pa \* T_a_in + ω_a_in \* h_fg;
h_w_in = C_pw \* T_w_in;
h_a_out = C_pa \* T_a_out + ω_a_out \* h_fg;
h_w_out = C_pw \* T_w_out;

% Display results
fprintf('Outlet air temperature: %.2f C\n', T_a_out);
fprintf('Outlet water temperature: %.2f C\n', T_w_out);
fprintf('Outlet air humidity ratio: %.4f\n', ω_a_out);


This code calculates the outlet temperatures and humidity ratio of the air and water streams, as well as the specific enthalpies of the streams. Note that this is a simplified model and does not take into account many factors that can affect the performance of a humidifier, such as heat losses, pressure drops, and non-ideal heat transfer.